The captain struck the decisive blow just moments after Giuseppe Pancaro appeared to have secured a draw for the visitors with a wonderful curling strike into the top corner.
Robbie Fowler and Djibril Cisse had scored either side of half-time to put the Reds two goals in front, before Andrea Pirlo whipped a trademark free-kick over the wall to get one back for the visitors on the hour mark.
Check out the best photos from the LFC Foundation charity match in our gallery below...