Pepe Reina was an unused substitute as holders Spain crashed out of the World Cup after a 2-0 defeat by Chile at the Maracana in Rio de Janeiro on Wednesday night.
After their opening day hammering by Holland, Xabi Alonso and co knew a win was a must.
However, Chile had other ideas as they produced a fantastic performance.
They took the lead after 19 minutes when Eduardo Vargas fired past Iker Casillas after superb play by Alexis Sanchez and Charles Aranguiz.
Then an error from Casillas led to a second goal. The Real Madrid stopper chose to punch away a free-kick rather than a simpl catch, and it was punished ruthlessly when Aranguiz brilliantly fired into the net for 2-0.
Chile now join Holland in qualifying for the next stage while Spain finish their 2014 World Cup campaign with a clash against Australia on Monday evening.