Pepe Reina was an unused substitute as holders Spain crashed out of the World Cup after a 2-0 defeat by Chile at the Maracana in Rio de Janeiro on Wednesday night.

After their opening day hammering by Holland, Xabi Alonso and co knew a win was a must.

However, Chile had other ideas as they produced a fantastic performance.

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They took the lead after 19 minutes when Eduardo Vargas fired past Iker Casillas after superb play by Alexis Sanchez and Charles Aranguiz.

Then an error from Casillas led to a second goal. The Real Madrid stopper chose to punch away a free-kick rather than a simpl catch, and it was punished ruthlessly when Aranguiz brilliantly fired into the net for 2-0.

Chile now join Holland in qualifying for the next stage while Spain finish their 2014 World Cup campaign with a clash against Australia on Monday evening.